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Dimethylsulfoxonium Methylide

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Dimethylsulfoxonium Methylide

Molecular formula: C3H8OS CAS# 5367-24-8
Categories: Organic compound
PubChem CID: 6396768 | ChemSpider ID: 4910091 | UNII-7Q604D1T2G
Names
English:
Corey's reagent
Corey-Chaykovsky reagent
Dimethyloxosulfonium methylide
Dimethylsulfoxonium Methylide
Methylenedimethyloxosulfur(VI)
Sulfur, dimethylmethyleneoxo-(CAS)
UNII:7Q604D1T2G
[Dimethyl(oxido)-λ6-sulfanylidene]methane(IUPAC)
dimethyl-methylidene-oxo-$l^{6}-sulfane(IUPAC)
dimethylsulfoxoniummethylide

Variants of the formula:

H2C=S<`|CH3><|CH3>=O
H\<|H>//S<_q4><_p4>//O
(CH3)2S(CH2)O
Elemental composition
Can't show the diagram.
Symbol Element Atomic weight Number of atoms Mass percent

Reactions in which Dimethylsulfoxonium Methylide is involved

  • [(CH3)3SO]I + NaH → (CH3)2S(CH2)O + NaI + H2