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Triiron dodecacarbonyl

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Triiron dodecacarbonyl

Molecular formula: C12Fe3O12 CAS# 17685-52-8
Categories: Coordination compounds , Inorganic matter
PubChem CID: 6096998 | ChemSpider ID: 453113 | CB3467620
Names
English:
Carbon monooxide - iron (4:1)
EINECS:241-668-5
Iron dodecacarbonyl
Triiron dodecacarbonyl [Wiki]
dodecarbonyltriiron
tetra-μ-carbonyl-1:2κ4C,1:3κ2C,2:3κ2C-octacarbonyl-1κ3C,2κ3C,3κ2C-triangulo-triiron(3 Fe—Fe)

Variants of the formula:

Fe3(CO)12
{}$L(.6)<`|0Fe><\0Fe><`/0Fe>$L()@:c(a,c,o)<_(A&a,N0,L1.5)C&c^-_(a0,N3)O&o^+>@(0,`)@c(30,`)@c(60,`)@c(90)@c(120,,`)@c(150,,`)@c(180,,`)@c(-150,,`)@c(-120,,`)@c(-90)@c(-60,`)@c(-30,`)
Fe_(x%a:.8,y-%h:1,d+)C<_(y-.5)O>_(x%b:2,y%h,d-)Fe_(x-%a,y-%h,w+)C<_(y-.5)O>_(x-%b,y%h,w-)$L(1.2)$slope(40)<_(A170,d+)OC><`\OC><`/wOC>_(x#1;4,y1.5)Fe<\CO><`/OC><|dC_(y.5)O><_(y-1,w+)C_(y-.5)O>_#4</CO><_(A10,d+)CO>\wCO
Elemental composition
Can't show the diagram.
Symbol Element Atomic weight Number of atoms Mass percent

Reactions in which Triiron dodecacarbonyl is involved

  • 3Fe2(CO)9 "70^oC"--> 3Fe(CO)5 + Fe3(CO)12
  • 3Fe(CO)5 "C2H5ONa"--> Fe3(CO)12"|v" + 3CO"|^"
  • 3H2Fe(CO)4 + 3H2O2 -> Fe3(CO)12 + 6H2O
  • Fe3(CO)12 "140-150^oC"--> 3Fe + 12CO
  • 3H2Fe(CO)4 + 3MnO2 + 3H2SO4 -> Fe3(CO)12 + 3MnSO4 + 6H2O